Liquids and Liquid Mixtures

Preface to the Third Edition1 Introduction 1.1 The Liquid State2 The Thermodynamic Properties 2.1 Summary of Thermodynamic Relations 2.2 Vapor Pressure 2.3 Mechanical Properties 2.4 Heat Capacities 2.5 Adiabatic Properties 2.6 Residual and Configurational Properties 2.7 van der Waals's Equation3 The Critical State 3.1 Thermodynamics of the Critical Point 3.2 Inequalities at the Critical Point 3.3 The Measurement of Critical Constants 3.4 Experimental Values of the Critical Exponents 3.5 Scaling the Free Energy4 The Thermodynamics of Liquid Mixtures 4.1 Introduction 4.2 Partial Molar Quantities 4.3 The Ideal Mixture 4.4 Thermodynamics of Non-ideal Mixtures 4.5 Tests for Consistency 4.6 Azeotropy 4.7 Fields and Densities 4.8 Thermodynamics of Partially Miscible Liquids 4.9 Exponents at the Critical Point of a Binary Mixture 4.10 Tricritical Points5 Excess Thermodynamic Functions 5.1 Introduction 5.2 The Experimental Determination of Excess Functions 5.3 Mixtures of Condensed Gases 5.4 Liquefied Natural-Gas Mixtures 5.5 Mixtures of the Higher Hydrocarbons 5.6 Mixtures Containing Halides 5.7 Mixtures Containing Fluorocarbons 5.8 Mixtures Containing Polar Liquids 5.9 Aqueous Mixtures 5.10 Mixtures of Quantum Liquids6 Fluid Mixtures at High Pressures 6.1 Introduction 6.2 Gas-Liquid Critical States of Binary Mixtures 6.3 High-Pressure Phase Equilibria: Type I Mixtures 6.4 High-Pressure Phase Equilibria: Type II and Type VI Mixtures 6.5 High-Pressure Phase Equilibria: Type III Mixtures 6.6 High-Pressure Phase Equilibria: Type IV and Type V Mixtures7 The Statistical Thermodynamics of Fluids 7.1 Intermolecular Forces 7.2 Molecular Distribution Functions 7.3 Molecular Correlation Functions 7.4 The Measurement and Calculation of Correlation Functions 7.5 The Principle of Corresponding States 7.6 Perturbation Theories: Spherical Molecules 7.7 Perturbation Theories: Non-Spherical Molecules8 The Statistical Thermodynamics of Mixtures 8.1 Introduction 8.2 Ideal and Random Mixtures 8.3 Mixtures of Spheres 8.4 The van der Waals Approximation 8.5 Perturbation Theories of Mixtures of Spherical Molecules 8.6 Excess Functions of Simple Mixtures 8.7 Mixtures of Alkanes 8.8 Perturbation Theories of Mixtures of Non-Spherical Molecules 8.9 Phase Equilibria at High Pressures 8.10 ConclusionsGeneral IndexIndex of Systems